The primary components of porcelain are clays, feldspar or flint, and silica, all characterized by small particle size. To create different types of porcelain, craftspeople combine these raw materials in varying proportions until they obtain the desired green (unfired) and fired properties.
Although the composition of clay varies depending upon where it is extracted and how it is treated, all clays vitrify (develop glassy qualities), only at extremely high temperatures unless they are mixed with materials whose vitrification threshold is lower. Unlike glass, however, clay is refractory, meaning that it holds its shape when it is heated. In effect, porcelain combines glass's low porosity with clay's ability to retain its shape when heated, making it both easy to form and ideal for domestic use. The principal clays used to make porcelain are china clay and ball clay, which consist mostly of kaolinate, a hydrous aluminum silicate.
Feldspar, a mineral comprising mostly aluminum silicate, and flint, a type of hard quartz, function as fluxes in the porcelain body or mixture. Fluxes reduce the temperature at which liquid glass forms during firing to between 1,835 and 2,375 degrees Fahrenheit (1,000 and 1,300 degrees Celsius). This liquid phase binds the grains of the body together.
Silica is a compound of oxygen and silicon, the two most abundant elements in the earth's crust. Its resemblance to glass is visible in quartz (its crystalline form), opal (its amorphous form), and sand (its impure form). Silica is the most common filler used to facilitate forming and firing of the body, as well as to improve the properties of the finished product. Porcelain may also contain alumina, a compound of aluminum and oxygen, or low-alkali containing bodies, such as steatite, better known as soapstone.
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